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Taskmaster
Technovore
Temugin
Thanos
Thinker
Thunderball
Titanium Man
Ultimo
Unicorn
Venom

Vibro
Vitriol
VOR/TEX
War Machine III
Whiplash - Anto Ivan Vanko
Whirlwind
White Dragon
Wong Chu
Wrecker
Yellow Claw
Taskmaster
Technovore
Temugin
Thanos
Thinker
Awesome Android made by the Mad Thinker
Thunderball
Awesome Android able to mimic Iron Man
Titanium Man - Boris Bullski
Ultimo
Titanium Man IM V1 #229 - Gremlin 
Unicorn
Venom and IM V1 #302
Unicorn - IM V1 #4
Vibro
Vitriol
VOR/TEX in cyberspace
War Machine III - Parnell Jacobs
VOR/TEX next level
VOR/TEX takes control of Tony Stark's body
VOR/TEX in the Modular armor fights Tony in the prototype armor
Whiplash - Anton Ivan Vanko
Whirlwind
White Dragon
Wong Chu
Wrecker and IM V1 #251
Yellow Claw
IM V3 #32